Keyword Author: chalcogens

Electrosynthesis of Bifunctional WS3-x/Reduced Graphene Oxide Hybrid for Hydrogen Evolution Reaction and Oxygen Reduction Reaction Electrocatalysis

A multitude of research into the application of transition-metal dichalcogenides as earth-abundant hydrogen evolution reaction (HER) electrocatalysts has been conducted. However, current synthetic methods generally deploy environmentally harmful chemicals and energy-consuming reaction conditions, despite the primary intent to attain renewable energy production. Here, the desirable properties of tungsten sulfide and reduced graphene oxide (rGO) have …

Electrosynthesis of Bifunctional WS3-x/Reduced Graphene Oxide Hybrid for Hydrogen Evolution Reaction and Oxygen Reduction Reaction Electrocatalysis Read More »

2H -> 1T Phase Engineering of Layered Tantalum Disulfides in Electrocatalysis: Oxygen Reduction Reaction

Tremendous attention is currently being paid to renewable sources of energy. Transition-metal dichalcogenides (TMDs) have been intensively studied for their promising catalytic activities in the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR). In this fundamental work, we explored the catalytic properties of TMD family members 2HTaS(2) and 1T TaS2. Our findings reveal …

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Cytotoxicity of Exfoliated Layered Vanadium Dichalcogenides

Transition-metal Group 5 vanadium dichalcogenides have shown promising properties for many applications, such as batteries, capacitors, electrocatalysts for hydrogen production and many more. However, their toxicological effects have not yet been well understood. Here, we studied the cytotoxicity of exfoliated VS2, VSe2 and VTe2 by incubating various concentrations of the materials with human lung carcinoma …

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Layered Post-Transition-Metal Dichalcogenides (X-M-M-X) and Their Properties

A(III)B(VI) chalcogenides are an interesting group of layered semiconductors with several attractive properties, such as tunable band gaps and the formation of solid solutions. Unlike the typically sandwiched structure of transitionmetal dichalcogenides, A(III)B(VI) layered chalcogenides with hexagonal symmetry are stacked through the X-M-M-X motif, in which M is gallium and indium, and X is sulfur, …

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Graphene-Amorphous Transition-Metal Chalcogenide (MoSx, WSx) Composites as Highly Efficient Hybrid Electrocatalysts for the Hydrogen Evolution Reaction

Layered transition-metal dichalcogenides (TMDs) show promising electrocatalytic properties towards the hydrogen evolution reaction (HER). A series of graphene-amorphous TMD composites were prepared under hydrothermal conditions. Materials with varying contents of MoSx and WSx were synthesized from ammonium tetrathiomolybdate and ammonium tetrathiotungstate precursors in the presence of graphene oxide and diethylene glycol as a reducing agent. …

Graphene-Amorphous Transition-Metal Chalcogenide (MoSx, WSx) Composites as Highly Efficient Hybrid Electrocatalysts for the Hydrogen Evolution Reaction Read More »