Prospects for Functionalizing Elemental 2D Pnictogens: A Study of Molecular Models

Despite the intense amount of attention and huge potential of 2D-layered pnictogens for applications in chemistry, physics, and materials science, there has yet to be a robust strategy developed to systematically functionalize them to tailor their properties. This is due to a number of factors, including practical instability toward ambient conditions, difficulty in characterizing modified materials, and also more inherent reactivity issues. Here, avenues for functionalization are discussed using examples of molecular models from the wider literature, along with their possible advantages and likely pitfalls. Finally, a critical appraisal of the current field and its future is offered.